Unbinding and preunbinding in surfactant solutions.

نویسندگان

  • S Komura
  • N Shimokawa
  • T Kato
چکیده

We propose models for the first-order unbinding transition of lyotropic lamellae in surfactant solutions. The coupling between the surfactant volume fraction and the elastic degree of freedom is considered so that the net attractive interaction between the surfactant molecules is enhanced. The elastic degree of freedom can be either (i) a membrane elastic degree of freedom or (ii) a bulk elastic degree of freedom. The phase behaviors of these two models are analyzed. For both cases, the unbinding transition becomes first order when the coupling is strong enough. We determine the associated preunbinding line which separates two lamellar phases having different repeat distances.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 124 3  شماره 

صفحات  -

تاریخ انتشار 2006