Unbinding and preunbinding in surfactant solutions.
نویسندگان
چکیده
We propose models for the first-order unbinding transition of lyotropic lamellae in surfactant solutions. The coupling between the surfactant volume fraction and the elastic degree of freedom is considered so that the net attractive interaction between the surfactant molecules is enhanced. The elastic degree of freedom can be either (i) a membrane elastic degree of freedom or (ii) a bulk elastic degree of freedom. The phase behaviors of these two models are analyzed. For both cases, the unbinding transition becomes first order when the coupling is strong enough. We determine the associated preunbinding line which separates two lamellar phases having different repeat distances.
منابع مشابه
Drag Reduction by Surfactant Solutions in Gravity Driven Flow Systems
Efflux time measurements are carried out for gravity draining of a liquid from a large cylindrical tank (where the flow is essentially laminar) through single exit pipe in the absence and presence of Cetyl Pyridinium Chloride (CPC) surfactant solutions. The variables considered are initial height of liquid in the tank, dia. of tank, length of the exit pipe and concentration of surfactant. T...
متن کاملDrag Reduction by Anionic Surfactant Solutions in Gravity Driven Flow System
This paper presents efflux time experiments performed in the absence and presence of aqueous solutions of Drag Reducing Agents (DRAs) when a liquid is emptied from a large open cylindrical storage tank through an exit piping system. The drag reducing agents studied are Dodecyl benzene sulfonate anionic surfactant and a mixed solution of surfactant and sodium chloride counter ion. The variab...
متن کاملPhotocatalytic Degradation of an Anionic Surfactant by Tio2 Nanoparticle under UV Radiation in Aqueous Solutions
In this paper the photocatalytic degradation of the anionic surfactant, linear alkylbenzene sulfonicacid (LABSA) was investigated using UV radiation in the presence of TiO2. Our findingsdemonstrate that various parameters exert their individual influence on the photocatalytic degradationof surfactant in wastewaters. The mentioned parameters have been categorized as follow: the initialpH of the ...
متن کاملThe Effect of Type and Concentration of Surfactant and Ligand on Uranium (VI) Cloud-Point Extraction (CPE) from Aqueous Solutions (Short Communication)
In this article cloud-point extraction (CPE) was used with chelating agent to extract uranium from aqueous solutions. The methodology used is based on the formation of metal complexes soluble in a micellar phase of surfactant. The metal ions complexes are then extracted into the surfactant-rich phase at a temperature above the cloud-point temperature. The effect of type of surfactants and ligan...
متن کاملSpectrophotometric Determination of Acidity Constants of Thiamine in Water, Water-Triton X-100 Micellar Media Solutions
In this work the acidity constants of Thiamine in water and water-Triton X-100 micelle media solutions, at 25 °C, have been determined spectrophotometrically. To evaluate the pH- absorbance data, a resolution based on the combination of soft-and hard-modeling is applied. The acidity constants of all related equilibria are estimated using the whole spectral fitting of the collected data to a...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- The Journal of chemical physics
دوره 124 3 شماره
صفحات -
تاریخ انتشار 2006